EN呋喃樹脂msds
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1、呋喃樹脂液 MSDS報(bào)告(化學(xué)品安全技術(shù)說明書) Furan Resin Liquid MSDS Report (Material Safety Data Sheet) 發(fā)布時(shí)間:2010-09-29 Date of issue: September 29, 2010 第一部分:化學(xué)品名稱 Part 1: Chemical Name 化學(xué)品中文名稱:呋喃樹脂液 Chinese name: 呋喃樹脂液 化學(xué)品英文名稱:Furan Resin Liquid English name: Furan Resin Liquid 主要成份:糠醇(C5H6O2)、糠醛(C6
2、H4O2)及其高聚物 Main ingredients: Furfuryl alcohol (C5H6O2), Furfural (C6H4O2) and their high polymers. 第二部分:成分/組成信息 Part 2: Composition/Information on Ingredients 有害物成分:糠醇(C5H6O2)、糠醛(C6H4O2)及其高聚物 Harmful ingredients: Furfuryl alcohol (C5H6O2), Furfural (C6H4O2) and their high polymers. 第三部分:危險(xiǎn)性概
3、述 Part 3: Hazards Summarizing 危險(xiǎn)性類別: Dangerousness classification: 健康危害:本品有弱刺激作用,可引起皮膚和上呼吸道輕度不適 Health hazards: This product has the weak irritating effect and may induce mild discomfort of skin and upper respiratory tract. 環(huán)境危害:對環(huán)境有危害,對水體可造成污染。 Environment hazards: This product may cause
4、 environmental damage, and especially may cause water pollution. 燃爆危險(xiǎn):本品可燃。 Fire and explosion hazards: This product is flammable. 第四部分:急救措施 Part 4: First Aid Measures 皮膚接觸:脫去污染的衣著,用肥皂水和清水徹底沖洗皮膚。 Skin exposure: Take off the polluted clothes, and flush thoroughly skin with soap water and c
5、lean water. 眼睛接觸:提起眼瞼,用流動(dòng)清水或生理鹽水沖洗。就醫(yī)。 Eye contact: Raise eyelid, flush with fluid clean water or normal sodium and go to a doctor. 吸入:迅速脫離現(xiàn)場至空氣新鮮處。保持呼吸道通暢。 Inhaled: Leave the scene quickly to fresh air and keep respiratory tracts unobstructed. 食入:飲足量溫水,催吐。就醫(yī)。 Swallowed: Drink enough warm
6、 water to induce vomiting and seek medical advice. 第五部分:消防措施 Part 5: Fire Fighting Measures 危險(xiǎn)特性:遇明火、高熱可燃。 Hazard characteristics: It is flammable in case of open fire and high heat. 有害燃燒產(chǎn)物:一氧化碳、二氧化碳 Hazardous combustion products: CO, CO2. 滅火方法:將容器從火場移至空曠處。處在火場中的容器若已變色或從安全泄壓裝置中產(chǎn)生滅火劑:泡沫、二氧化
7、碳、干粉、砂土。用水滅火無效,有害燃燒產(chǎn)物:一氧化碳、二氧化碳。 Extinguishing method: Transfer the containers from the scene of fire to open space. If the containers in the fireground have changed colors or generate extinguishant from the safety relief device, use foam, CO2, dry powder and sand to extinguish the fire. If trying
8、to extinguish the fire with water, it will be ineffective. Hazardous combustion products: CO, CO2. 第六部分:泄漏應(yīng)急處理 Part 6: Accidental Release Measures 應(yīng)急處理:隔離泄漏污染區(qū),限制出入。切斷火源。建議應(yīng)急處理人員戴防塵口罩。不要直接接觸泄漏物。小量泄漏:收集于干燥、潔凈、有蓋的容器中。大量泄漏:收集回收或運(yùn)至廢物處理場所處置。 Emergency measures: Isolate the contaminated areas of leak
9、age and restrict access. It is advised the emergency personnel should wear dust mask and should not contact the leakage directly. In case of small amount of leakage, collect it in a dry and clean container with lid. In case of large amount of leakage, collect and recycle it or transport it to a wast
10、e treatment plant for disposal. 第七部分:操作處置與儲(chǔ)存 Part 7: Handling and Storage 操作注意事項(xiàng):操作人員應(yīng)經(jīng)過專門培訓(xùn),嚴(yán)格遵守操作規(guī)程。建議操作人員佩戴(口罩),遠(yuǎn)離火種、熱源,工作場所嚴(yán)禁吸煙。使用通風(fēng)系統(tǒng)和設(shè)備。避免與氧化劑接觸。配備相應(yīng)品種和數(shù)量的消防器材及泄漏應(yīng)急處理設(shè)備。倒空的容器可能殘留有害物。 Handling notes: All handling personnel should be specially trained, and should be in strict accordance wi
11、th the handling rules. It is recommended all handling personnel wear masks and stay away from fire and heat. It is strictly prohibited to smoke at work. Use ventilating system and equipment. Keep the chemicals away from any oxidant. Provide relevant types and quantity of firefighting equipment and l
12、eakage emergency equipment. There may be residual hazards in any emptied container. 儲(chǔ)存注意事項(xiàng):儲(chǔ)存于陰涼、通風(fēng)的庫房。遠(yuǎn)離火種、熱源。防止陽光直射。包裝密封。應(yīng)與氧化劑、食用化學(xué)品分開存放,切忌混儲(chǔ)。配備相應(yīng)品種和數(shù)量的消防器材。儲(chǔ)區(qū)應(yīng)備有合適的材料收容泄漏物。 Storage notes: Store it in cool, ventilated storehouse. Keep away from fire and heat. Avoid direct sunlight. The packagin
13、g should be well sealed. Separate it from oxidant and food chemicals, and no mixed storage is allowed. Provide relevant types and quantity of firefighting equipment. The storage area should be provided with stuff suitable for containing leakage. 第八部分:接觸控制/個(gè)體防護(hù) Part 8: Exposure Control/Personal Pr
14、otection 職業(yè)接觸限值:未制定標(biāo)準(zhǔn) Professional exposure limits: Not regulated. 中國MAC(mg/m3):未制定標(biāo)準(zhǔn) China MAC (mg/m3): Not regulated. 前蘇聯(lián)MAC(mg/m3):未制定標(biāo)準(zhǔn) Former Soviet Union MAC (mg/m3): Not regulated. 監(jiān)測方法:嚴(yán)加密閉,提供充分的局部排風(fēng)。 Monitoring methodology: Be strictly airtight and provide full local exhaust. 呼吸
15、系統(tǒng)防護(hù):口罩 Respiratory system protection: respirators 眼睛防護(hù):護(hù)目鏡 Eye protection: goggles 其他防護(hù):工作現(xiàn)場禁止吸煙、進(jìn)食和飲水。工作完畢,淋浴更衣。保持良好的衛(wèi)生習(xí)慣 Other protections: No smoking, feeding and drinking at work. Take a shower and change clothes after work. Maintain good health habits. 第九部分:理化特性 Part 9: Physical and C
16、hemical Properties 主要成分:糠醇、糠醛及其高聚物 Main ingredients: Furfuryl alcohol, Furfural and their high polymers. 外觀與性狀:棕褐色液體 Appearance and properties: brown liquid pH:6.5~7 沸點(diǎn)(℃):161.7~171 Boiling point (℃): 161.7~171 相對密度(水=1):1.19 Relative density (water=1): 1.19 相對蒸氣密度(空氣=1):無資料 Relative va
17、por density (air=1): No useful information available up to date. 飽和蒸氣壓(kPa):無資料 Saturation vapor pressure (kPa): No useful information available up to date. 燃燒熱(kJ/mol):無資料 Combustion heat: No useful information available up to date. 閃點(diǎn)(℃):無資料 Flash point (℃): No useful information available
18、 up to date. 引燃溫度(℃):392℃ Ignition temperature (℃): 392℃ 溶解性:無資料 Dissolubility: No useful information available up to date. 主要用途:適宜用作耐水性膠黏劑、防腐蝕膠泥、襯里、浸漬液、玻璃鋼。 Main application: Suitable to be used as water-resisting adhesive, anti-corrosion mastic, lining, impregnant and glass fiber reinforced
19、plastics. 第十部分:穩(wěn)定性和反應(yīng)活性 Part 10: Stability and Reactivity 熱分解及要避免的情況:如果按照規(guī)則使用則不會(huì)分解 Thermal decomposition and conditions to avoid: No decomposition will occur if used in accordance with the rules. 危險(xiǎn)的反應(yīng):未有已知危險(xiǎn)反應(yīng) Hazardous reaction: None. 危險(xiǎn)的分解產(chǎn)品:未有已知危險(xiǎn)分解產(chǎn)品 Hazardous decomposition product
20、s: None. 第十一部分:毒理學(xué)資料 Part 11: Toxicological Information 糠醇(C5H6O2)、糠醛(C6H4O2)及其高聚物 Furfuryl alcohol (C5H6O2), Furfural (C6H4O2) and their high polymers 主要的刺激性影響: Main irritating effects: 皮膚:刺激皮膚的粘膜 Skin: It has irritating effect on skin mucous membrane. 眼睛: Eye: 致敏作用:沒有已知的至敏影響 Sensit
21、ization: None. 該產(chǎn)品顯示以下危險(xiǎn):刺激性的 This product has following hazards: irritation. 第十二部分:生態(tài)學(xué)資料 Part 12: Ecological Information 生態(tài)毒性的影響:該物質(zhì)對環(huán)境有危害,應(yīng)特別注意對水體的污染 Ecotoxicity effect: This product is harmful to environment and special attention should be paid to its water pollution. 第十三部分:廢棄處置 Part
22、 13: Disposal Information 廢棄處置方法:在能利用的地方重復(fù)使用容器或在規(guī)定場所集中處理 Waste disposal method: Reuse containers where applicable or dispose of them in a centralized way in a place as required. 廢棄注意事項(xiàng):不能將該產(chǎn)品與普通垃圾一起丟棄,不要讓該產(chǎn)品接觸污水系統(tǒng) Disposal considerations: This product should not be discarded together with gener
23、al refuse and should be kept away from sewage system. 第十四部分:運(yùn)輸信息 Part 14: Transport Information 危險(xiǎn)貨物編號:90 Code of dangerous goods: 90 UN編號:3082 UN No.: 3082 包裝標(biāo)志:II I Packing mark: II I 包裝類別: Packing group: 包裝方法:螺紋口玻璃瓶、鐵蓋壓口玻璃瓶、塑料瓶或金屬桶(罐)外普通木箱;螺紋口玻璃瓶、塑料瓶或鍍錫薄鋼板桶(罐)。 Packing method: Thre
24、ad screw neck vial, gland vial, plastic bottle or metal drum (can) enclosed by common wooden case; thread screw neck vial, plastic bottle or tinned steel sheet drum (can) 運(yùn)輸注意事項(xiàng):運(yùn)輸前應(yīng)先檢查包裝容器是否完整、密封,運(yùn)輸過程中要確保容器不泄漏、不倒塌、不墜落、不損壞。嚴(yán)禁與酸類、氧化劑、食品及食品添加劑混運(yùn)。運(yùn)輸時(shí)運(yùn)輸車輛應(yīng)配備相應(yīng)品種和數(shù)量的消防器材及泄漏應(yīng)急處理設(shè)備。運(yùn)輸途中應(yīng)防曝曬、雨淋,防高溫。 Cauti
25、on during transport: Check first whether packing containers are complete and sealed before transport, and make sure no leakage, collapse, fall and damage occur to containers during transport. Transport vehicles should be provided with relevant types and quantity of firefighting equipment and acciden
26、tal release treatment equipment. Avoid exposure under blazing sun, rain and high temperature in transit. 第十五部分:法規(guī)信息 Part 15: Regulatory Information 產(chǎn)品的代號字母有危險(xiǎn)標(biāo)志: Product’s code letter with hazard symbol: Xn:有害 Xn: hazardous NL:對環(huán)境有危害 標(biāo)簽上辨別危險(xiǎn)的成份:糠醇(C5H6O2)、糠醛(C6H4O2) NL: Ingredients harmf
27、ul to environment that can be identified on the label: Furfuryl alcohol (C5H6O2), Furfural (C6H4O2) 危險(xiǎn)說明;直接接觸可刺激皮膚和上呼吸道。對水生環(huán)境可能造成一定的不良影響,如果吞下可能會(huì)造成消化道損傷。 安全說明:將容器存放在通風(fēng)良好的地方,禁止將該產(chǎn)品倒入排水管道內(nèi)。物料和容器集中收集處理 國家法規(guī):水危險(xiǎn)級別2(自我評估)對水是有危害的 第十六部份:其它資料 Part 16: Other Information 免責(zé)聲明:本化學(xué)品安全技術(shù)說明書的資料是依據(jù)我們相信可靠的來源
28、中獲得。但是我們所提供的數(shù)據(jù)并沒有保證、暗示、表達(dá)它的正確性。 Disclaimer: The information of this MSDS is obtained based on reliable source to the best of our knowledge and belief. However, we don’t guarantee, imply and express the correctness of the provided data. 相關(guān)危險(xiǎn)說明:可燃。 Notes on relevant dangers: flammable. 直接接觸可刺激皮膚和上呼吸道,對水生環(huán)境可能造成一定的不良影響,如果吞下可以會(huì)造成消化道損傷。 編制單位:湖北華寧防腐技術(shù)股份有限公司 Prepared by: Hubei Huaning Anticorrosion Technic Share Co., Ltd.
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