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Oxidize the ditch craft in dirty water handle of application and development
Summary: This text expatiated primarily the Carrousel oxidizes the construction, craft mechanism of the ditch and circulate the problem exsited in the process with the homologous the method of solution.Finally, introduce the Carrousel oxidize the latest research progress of the ditch and pointed out the future and main research direction.
Key phrase: The Carrousel oxidizes the ditch divideds by the phosphor takes off the nitrogen construction mechanism
Application and Development of Carrousel Oxidation Ditch Process on Wastewater Treatment
Abstract: The structure and the techniques of carrousel oxidation ditch process on nitrogen and phosphor removal are introduced in this paper. The problems inrunning and their corresponding resolvent are also pointed. At last, The authorshowed the up to date research improvement and the mainly future research dire-ction.
Key words: Carrousel; oxidation ditch; nitrogen and phosphor removal; structure;techniques
1. Foreword
Oxidize the ditch( oxidation ditch) again a continuous circulation spirit pond( Continuous loop reactor), is a live and dirty mire method a kind of to transform.Oxidizing the dirty water in ditch handles the craft be researched to manufacture by the hygiene engineering graduate school of Holland in the 50's of 20 centuries success.Since in 1954 at Dutch throw in the usage for the very first time.Because its a water fluid matter good, circulate the stability and manage convenience etc. technique characteristics, already at domestic and
international and extensive application in live the dirty water to is dirty to manage aqueously with the industry[1].
Current application than oxidize extensively the ditch type include:The ( Pasveer) oxidizes the ditch, the ( Carrousel) oxidizes the ditch, ( Orbal) oxidizes the ditch, the type of T oxidizes the ditch( three ditch types oxidize the ditch), the type of DE oxidizes the ditch to turn to oxidize the ditch with the integral whole.These oxidize the ditch because of the difference of esse in construction with circulating, therefore each characteristics[2].This text will introduce construction, mechanism, existent problem and its latest developments that Carrousel oxidize ditches primarily.
2. The Carrousel oxidizes the construction of the ditch
The Carrousel oxidize the ditch to be researched to manufacture by Dutch DHV company development in 1967.Oxidize the last the company of DHV in foundation of the ditch in the original Carrousel to permited specially the company EIMCO to invent again with its patent in the United States Carrousel 2000 system( see the figure ), realizes the living creature of the higher request takes off the nitrogen with divided by the function of .There has been in the world up to now more than 850 Carrousels oxidize the ditch with the Carrousel 2000 system are circulating[3].
From diagram therefore, the Carrousel oxidizes the ditch the usage the spirit of that definite direction control with shake up the device, face to mix with the liquid deliver the level speed, from but make drive the liquid of admixture that shake up is in oxidize ditch shut match outlet circulate flow.Therefore oxidize the ditch have the special hydraulics flows the , current complete mix with the characteristics of the type reactor, have the characteristics that push the flow type reactor again, the ditch inside exsits obviously of deliquescence oxygen density steps degree.Oxidizing the ditch cross
section is rectangle or trapezoids, the flat surface shape is many for oval, the ditch internal water is deep general for 2.5 ～ 4.5 ｍ , the breadth is deep compare for 2:1, also have the deep water amount to 7 ms of, ditch inside average speed in water current is 0.3 ms/ s.Oxidize ditch spirit admixture equipments contain surface spirit machine, the spirit of turn to brush or turn the dish and shoot to flow the spirit machine, pipe type spirit machine with promote take care of type spirit machine etc., match with in recent years usage still contain underwater push machine[4~6].
3. The Carrousel oxidizes the mechanism of the ditch
3.1 The Carrousel oxidizes the ditch handles dirty and aqueous principle
The at the beginning common Carrousel oxidizes the dirty water in inside in craft of the ditch direct with dirty mire in reflux together enter oxidize the ditch system.The surface spirit machine makes fuse in the liquid of admixture the density of the oxygen DO increases about 2 the 3 mgs/ L.Under this kind of well the term of the oxygen , the microorganism gets the enough deliquescence oxygen comes and go to divided by the BOD;At the same time, the ammonia were too oxidized nitrate with second nitrate, this time, mix with the liquid be placed in the oxygen appearance.In the spirit machine downstream, after water current be become by the swift flow appearance of the spirit District of even flow the appearance, the water current maintains in the minimum current velocity, guaranteeing the live and dirty mire be placed in the floats the appearance.( average current velocity>0.3 ms/ s)Oxidize microbially the process consumed to fuse the oxygen in the water, until the value of DO declines for zero, mixing with the liquid report the anoxia appearance.Versa nitric that turn the function through anoxia area, mix with the liquid enter to have the oxygen area, completing once circulating.That system inside, the
BOD declines the solution is a continuous process, the nitric turns the function to turn with the versa nitric the function take place in same pond.Because of structural restrict, this kind of oxidize the ditch although can then valid whereabouts BOD, divided by the phosphorus take off the nitrogenous ability limited[7].
For the sake of the acquisition better divided by the phosphorus take off the nitrogenous result, Carrousel 2000 systems increased a oxygen District before common Carrousel oxidize ditch with the unique oxygen area.( call again that the versa nitric in front turns the area)The dirty mire in all refluxes enters the anaerobic District with 10-30% dirty water, can under the anoxia with 10-30% carbon source term complete remaining of dirty mire in reflux inside nitric acid nitrogen to versa nitric to turn, creates for the unique oxygen pond of hereafter unique oxygen term.At the same time, anaerobic District inside of concurrently the sex germs convert the dissolubility BOD VFA, the germ acquire the VFA its assimilation PHB, the energy source needed solves in the phosphoric water and cause phosphatic releasing.The anaerobic District a water enters the inner part installs the unique oxygen area that have the mixer, the so-called unique oxygen is a pond inside to mix with liquid since have no the numerator oxygen, also have no the compound oxygen( nitric acid root), the here unique oxygen environment is next,70-90% dirty water can provide the enough carbon source, can make the germ of released the phosphorus well.The unique oxygen area connects behind the common Carrousel oxidizes the ditch system, further completing to do away with the BOD and take off the nitrogen with divided by the phosphorus .Finally, mix with the liquid transfer the dirty mire inside in oxidize ditch enrich oxygen area eject, while enriching the oxygen environment germ surfeit, phosphorus from the water, ejecting the system with the dirty mire in surplus.Like this, in Carrousel 2000
systems, than completed to do away with the BOD, COD with take off at the same time goodly the nitrogen divided by the phosphorus .
Synthesizing and dirty water in the river City , long sand City decontamination center[s of the dirty the factory of water in the first in Kunming of adoption that crafts handles the movement result of the factory therefore:Through Carrousel 2000 system after handling, the BOD, COD, SS does away with the rate to all come to a 90% above, the TN does away with the rate comes to a 80%, the TP does away with the rate to also come to a 90%.
3.2 The Carrousel oxidizes the ditch divideds by the phosphorus takes off the nitrogenous influence factor.
Affecting the Carrousel oxidizes the ditch divideds by the phosphoric factor is dirty mire , nitrate density and quality densities primarily.The research expresses, being total and dirty mire as 11% that a hour biggest phosphorus 4% with deal is its fuck dirty mire deal within live and dirty mire, keep for the the germ physical endowment measures, but when dirty mire over 15 d hour dirty mire the inside is biggest to contain the obvious descent in deal in phosphorus , canning not reach the biggest divideding by the result of phosphorus on the contrary.Therefore, prolong persistently the dirty mire ( for example 20ds,25ds,30ds) is to have no necessary, proper choose to use within the scope of 8~15 d.At the same time, high nitrate density with low quality density disadvantage in divided by the process of phosphorus .
Affecting the Carrousel oxidizes the ditch takes off the nitrogenous and main factor is DO, nitrate density and carbon source densities.The research expresses, oxidizing the ditch inside exsits deliquescence oxygen density steps degree namely the good oxygen area DO attains 3~3.5 mgs/ L, the anoxia area DO attains 0~0.5 mgs/ L is a prior condition to take place nitric turn reaction and versa nitrics
turn the reaction.At the same time, ample carbon source and higher C/ the N ratio benefits to take off to complete nitrogenously[7].
4. The Carrousel oxidizes problem and solution methods of the ditch esse.
Though the Carrousel oxidizes the ditch has a water fluid matter good, the anti- pounds at the burthen ability strong, divided by the phosphorus take off the nitrogen efficiency. But, in physically of movement process, still exsits a series of problem.
4.1 Dirty mire inflation problem
When discard the aquatic carbohydrate more, the N, P contains the unbalance of deal, the pH value is low, oxidizing the dirty mire in inside in ditch carries high, fuse the oxygen density the shortage, line up the mire not etc. causes easily dirty mire in germ in form in silk inflation;Not the dirty mire in germ in form in silk inflation takes place primarily at the waste water water temperature is lower but the dirty mire carries higher hour.The microbial burthen is high, the germs absorbed the large quantity nourishment material, is low because of the temperature, metabolism the speed is slower, accumulating the rises large quantity is high to glue sexual and many sugar materials, making the surface of the live and dirty mire adhere to the water to increase consumedly, SVI the value is very high, becoming the dirty mire inflation.
Cause that aim at the dirty mire inflation, can adopt the different counterplan:From the anoxia, water temperature high result in of, can enlargement tolerance or lower into the water measures to alleviate burthen, or the adequacy lowers the MLSS( control dirty mire reflux measure), making need the oxygen measures decrease;If the dirty mire carries high, can increase MLSS, to adjust the burthen, necessity the hour can stop into the water, stuffy a period of time;Can pass the hurl add the nitrogen fertilizer, phosphorus fatty, adjust the admixture
nourishment in the liquid material equilibrium( BOD5:N:P=100:5:1);The value of pH over low, can throw to add the lime regulate;Bleach the powder with the liquid chlorin( press to fuck 0.3% of the dirty mire~0.6% the hurl adds), can repress the silk form germ breed, controling the dirty mire in combinative water inflation[11].
4.2 Foam problem
Because entering to take the grease of large quantity in the water, handling system can't completely and availably its obviation, parts of greases enriches to gather in in the dirty mire, through turn to brush the oxygen agitation, creation large quantity foam;The mire is partial to long, the dirty mire is aging, and also easy creation foam.Spray to pour the water or divided by with the surface the of do away with the foam, in common use divided by the an organism oil, kerosene, the oil of silicon, throw deal as 0.5~1.5 mgs/ L.Pass to increase dirty mire in pond in spirit in density or adequacies let up the tolerance of , also can control the foam creation effectively.When contain the live material in surface in the waste water more, separate with the foam easily and in advance method or other methods do away with.Also can consider to increase to establish a set of divideding by the oil device moreover.But enhance most importantly the headwaters manage, reducing to contain the oil over the high waste water and other poisonous waste water of into[12].
4.3 Float the problem on the dirty mire
When contain in the waste water the oil measures big, whole system mire quality become light, can't like to control very much in operate process its at two sink the pond stop over time, resulting in the anoxia easily, producing the corrupt and dirty mire ascend to float;When spirit time over long, take place in pond the high degree nitric turn the function, making nitrate density high, at two sink the
versa nitric in easy occurrence in pond turn the function, creation nitrogen spirit, make dirty mire ascend float;Moreover, contain the oil in the waste water?
Take place the dirty mire ascend after floating should pause enter water, broke off or dirty mire in clearance, judge the clear reason, adjust the operation.The dirty mire sinks to decline the sex bad, can throw to add of oagulate or sloth materials, the improvement precipitates the sex;Such as enter the water carries big let up into the water measures or the enlargement reflux measures;Such as the dirty mire grain small lower the spirit machine turn soon;If discovers versa nitric turning, should let up the tolerance , enlarge the reflux or row the mire measures;If discover the dirty mire is corrupt, should enlargement tolerance, the clearance accumulates the mire, and try the ameliorative pond internal water dint term[12].
4.4 Current velocity is not all and the dirty mire sinks to accumulate the problem
In Carrousel oxidize ditch, for acquiring its special admixture with handles result, mix with liquid must with certain current velocity is in ditch circulate flow.Think generally, the lowest current velocity should should attain for an average current velocity for, doing not take place sinking accumulating 0.3~0.5 ms/ s.The spirit equipments that oxidize the ditch is general to turn to brush for the spirit of to turn the dish with the spirit of , turning to brush of immerse to have no depth for 250~300 mms, turn the dish immerse to have no depth for 480~530 mms.With oxidize the ditch water the deep(3.0~3.6 ms) comparing, turn to brush occupied the deep 1/10~ in water 1/12, turned the dish to also occupy the 1/6~ only 1/7, therefore result in to oxidize the ditch upper part current velocity bigger( roughly 0.8~1.2 ms, even larger), but the bottom current velocity is very small( especially at the water is deep 2/3 or 3/4 below, mix with the
liquid has no current velocity almost), causing ditch bottom large quantity accumulate the mire( sometimes accumulate the mire thickness amount to a 1.0 ms), the valid capacity that reduced to oxidize the ditch consumedly, lowered to handle result, affected a water fluid matter.
Adding the top, downstream leads to flow the plank is a valid method that ameliorative current velocity distribute, increases the oxygen ability with the most convenient measure.The upper stream leads to flow the plank installs at be apart from to turn the 4.0 places( upper stream) ： dish( turn to brush) axis, lead to flow plank high degree as the deep 1/5~ in water 1/6, combine the perpendicularity install in the surface;The downstream leads to flow the plank installs at be apart from to turn dish( turn to brush) axis 3.0 ms.Leading to flow knothole material can use metals or glass steels, but regard glass steel as good.Lead to flow the plank compares with other ameliorative measure, can't not only increase the motive consumes with revolves cost, but also can still than significantly exaltation 充 oxygen ability with theories motive efficiency[13].
Moreover, pass in the spirit on board swim to establish the underwater push machine can also turn to the spirit of the liquid of admixture that brush the bottom low speed area circulates to flow to rise positive push function, from but the solution oxidizes the problem that low and dirty mire in current velocity in bottom in ditch sink accumulates.Establish the underwater push machine useds for exclusively the push mixs with the liquid can make movement method that oxidize the ditch much more vivid, this for economy energy, lift the high-efficiency having the very important meaning[14].
5. The Carrousel oxidizes the development of the ditch
Because the dirty water handles standard inside to divided by the phosphorus take off the nitrogenous request more and more strict,
the development that Carrousel further oxidized the ditch to also get.Current, the research and application includes morely below two category type:Tiny bore spirit type Carrousel 2000 systems, Carrousel 3000 system.
5.1 Tiny bore spirit type Carrousel 2000 system
Tiny bore spirit type Carrousel 2000 tiny bore in adoption in system spirit( provide oxygen equipments as the drum breeze machine), the tiny bore spirit machine can produce the diameter of large quantity as a surface for or so and small spirit steeping, this consumedly increases spirit bubble accumulates, undering the certain circumstance in capacity in pond make the oxygen transfer the gross measures aggrandizement.( if deep increment in pond, its spread the quality efficiency will be higher)Produce the technique ability of the factory house according to the current drum breeze machine, the valid water of the pond is deep biggest amounting to a 8 ms, therefore can select by examinations according to the different craft request the fit water is deep.The tradition oxidizes the ditch pushes to flow is to make use of to turn to brush, turn a disc or pour the umbrella type form machine realizes of, its equipments utilization is low, the motive consumes big.Tiny bore spirit type Carrousel 2000 systems then adopted the underwater pushes the way that flow, rises to dive the propeller the leaf the motivation that round creation the direct function namely in the of water, at push to flow the function to can keep dirty mire from sinking to decline effectively again at the same time.As a result, the adoption dives the propeller since lower the motive consume, making mire water got again to mixs with adequately.
Seeing from water power characteristic, tiny bore spirit type Carrousel 2000 systems are wreaths form the fold flows the pond type, concurrently pushing the flow type with complete mix with the type
flows .In regard to whole oxidize ditch, can think that oxidize the ditch is a complete mix with spirit pond, its density variety coefficient smallest even can neglect to do not account, enter the water will get the dilution quickly, therefore it have the very strong anti- pounds at the burthen ability.But have oxidize ditch inside of a certain very much the some pushing the characteristic of the flow type, in the nearby district in downstream in machine in spirit inDO density higher, but along with increase with spirit machine distance continuously then the density of DO lowers continuously.( appear the anoxia area)This kind of structure method makes friendly oxygen in area in anoxia area exsited to build the thing inside , making use of its water power characteristic well, coming to an efficiently the living creature takes off the nitrogenous purpose.
Tiny bore spirit type Carrousel 2000 system though have the oxygen ability strong, divided by the phosphorus take off the nitrogen effective, cover the area little